Determination of ultra-trace gold in natural water by graphite furnace atomic absorption spectrophotometry after in situ enrichment with thiol cotton fiber

A simple method of determining ultra-trace Au in natural water was presented by using graphite furnace atomic absorption spectrophotometry (GFAAS) after in situ enrichment with thiol cotton fiber (TCF). The sample solution was adjusted to pH 1.5-2.0 with HCl, then the water sample was passed through a column packed with 0.10-0.20 g TCF and the flow rate was controlled at 20-40 ml min⁻¹. The effects of interferences, such as complexing and oxidizing agents and other elements adsorbed on TCF were overcome by chemical treatments prior to the desorption of Au. The adsorbed Au was adsorbed with 2.0 ml hot acid, then it was extracted with 1.00 ml methyl isobutylketone (MIBK). For a 5 l water sample, the detection limit of Au is 0.02 ng l⁻¹. The relative standard deviation (R.S.D.) for the determination of 1.44 ng l⁻¹ Au was 9.4%.The method was applied to determine ultra-trace Au both in suspended phase and soluble phase in natural water, the concentrations of total Au in natural water samples range from 0.51 to 67.82 ng l⁻¹. The recovery of added 0.50-6.00 ng l⁻¹ Au was 80-95%. The method is useful in prospecting for Au deposits by means of hydrogeochemical methods. The enrichment is carried out in the field, and then the determination of Au is completed later in the laboratory.     

New Kamenev-type oscillation criteria for second-order nonlinear differential equations with damping

Some new oscillation criteria are established for the nonlinear damped differential equation (r(t)y′)′+p(t)y′+q(t)f(y)=0 that are different from most known ones in the sense that they are based on a class of new functions Φ(t,s,r) defined in the sequel. Our results are sharper than some previous results which can be seen by the examples at the end of this paper.     

On Romanoff's constant

In 1934, Romanoff proved that there are a positive proportion natural numbers which can be expressed as the sum of a prime and a power of 2. In this paper, a quantitative version of this theorem is given. We show that the proportion is larger than 0.0868 and for a positive proportion of odd integers the number of such representations is between 1 and 16.     

D-N交替法与Schwartz交替法的收敛关系分析

This paper has demonstrated that the Schwartz alternating process must converge if D-N alternating process has converged. Its technique is that the overlapping regions in Schwartz alternating process are considered as independent domains, then Schwartz alternating process could be transformed into D-N alter-nating process. Finally the convergence estimation of Schwartz alternating process could be obtained. The results show that its convergence rate is same as that of D-N alternating process.     

双光束相干控制产生多次谐波的实验验证

利用两束相干度可改变的飞秒脉冲光对产生的五次谐波的强度特性进行了研究，发现谐波信号的强度随相干程度的增大而增加，谐波信号的最大值相对于相干零点(双光束相干度最大处)是非对称的，从而证明了合成的激光脉冲波形变化对谐波信号的影响.同时对谐波的受激放大理论进行了初步的实验探索和展望. 关键词： 五次谐波 波形变化 相干 受激放大     

IMPULSIVE CONTROL OF A FISHERY SYSTEM

This paper uses the method of linear approximation for impulsive systems and gets a theorem which guarantees a fishery modei to be asymptotically stable at its equilibrium point and gives the ecological explanation.     

双驱动x射线激光等离子体能谱特性研究

用时间积分空间分辨的平晶千电子伏谱仪测量了钽激光等离子体发射波长范围为045— 075nm的软x射线能谱，精确测量和准确辨认出类镍、类钴和类铁离子的共振线及类镍离子 的内壳层跃迁线-对实验结果处理，获得了辐射线谱的强度-通过谱线比率的诊断推断脉冲激 光时差对等离子体状态的影响，至少也可部分解释激光上能级的粒子数及等离子体的 电离程度- 关键词： 离子谱特性 软x线能谱强度 谱线辨认     

Ab-initio molecular dynamics simulation on nano-system under external pressure

A new constant-pressure molecular dynamics (MD) method is developed to simulate the dynamic behavior and structure transition of finite system under external pressure. In this method, no artificial parameter is introduced and the computation overheads are very small. As an application, a hard-soft transition of single wall carbon nanotube (SWCNT) under external pressure is found, which is in agreement with the experiments.

     

神光Ⅱ上柱形黑腔辐射驱动冲击波

利用神光Ⅱ的八路三倍频激光装置，驱动柱形黑腔产生的x 射线作辐射源驱动台阶铝样品产生冲击波，获得了清晰的冲击波图像，通过冲击波过台阶样 品的时间差获得冲击波速度和压力分别为31.2km/s和17.5×10⁵MPa.采用软x射线能谱 仪通过激光注入孔测量的辐射温度与采用冲击波法测量辐射温度的结果一致. 关键词： 冲击波 辐射驱动 辐射温度